Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers

Simple item page
dc.contributor.authorFarka, Dominikcs
dc.contributor.authorCigánek, Martincs
dc.contributor.authorVeselý, Dominikcs
dc.contributor.authorKalina, Lukášcs
dc.contributor.authorKrajčovič, Jozefcs
dc.coverage.issue37cs
dc.coverage.volume9cs
dc.date.accessioned2025-03-28T07:43:01Z
dc.date.available2025-03-28T07:43:01Z
dc.date.issued2024-09-03cs
dc.description.abstractThe anisotropic nature of charge transport through organic materials requires high control over the self-assembly of the organic materials. This is particularly so for conductive polymers, where transport occurs mainly along the polymers' backbone. Herein, we demonstrate the use of self-assembled monolayers (SAMs) to influence the self-assembly of poly(3-adamantylmethylthiophene). We employ two different SAMs, which interact with either the adamantyl- or the thiophene-functionality, respectively, and acquire distinct topologies as compared to the unmodified Au(111) surface. We compare these results with unmodified glass and mica (muscovite) surfaces, which are typically employed in the field of optoelectronics. We prove the usefulness and applicability of epitaxial effects and adamantyl substituents for organic electronics. This presents a viable way toward improved electronic performance for the field as a whole.en
dc.formattextcs
dc.format.extent38733-38742cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationACS OMEGA. 2024, vol. 9, issue 37, p. 38733-38742.en
dc.identifier.doi10.1021/acsomega.4c04616cs
dc.identifier.issn2470-1343cs
dc.identifier.orcid0000-0002-1738-3410cs
dc.identifier.orcid0000-0002-8764-7653cs
dc.identifier.orcid0000-0001-8127-8175cs
dc.identifier.orcid0000-0002-7495-1787cs
dc.identifier.other189619cs
dc.identifier.scopus55255338000cs
dc.identifier.urihttps://hdl.handle.net/11012/250686
dc.language.isoencs
dc.publisherAMER CHEMICAL SOCcs
dc.relation.ispartofACS OMEGAcs
dc.relation.urihttps://pubs.acs.org/doi/full/10.1021/acsomega.4c04616cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/2470-1343/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectSelf-assemblyen
dc.subjectadamantaneen
dc.subjectmonolayersen
dc.subjectorganic electronicsen
dc.titleEpitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayersen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-189619en
sync.item.dbtypeVAVen
sync.item.insts2025.03.28 08:43:01en
sync.item.modts2025.03.28 08:32:58en
thesis.grantorVysoké učení technické v Brně. Fakulta chemická. Ústav chemie materiálůcs
thesis.grantorVysoké učení technické v Brně. Fakulta chemická. Ústav chemie a technologie ochrany životního prostředícs
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
farkaetal2024.pdf
Size:
13.95 MB
Format:
Adobe Portable Document Format
Description:
file farkaetal2024.pdf
Download
Collections
Ústav chemie a technologie ochrany životního prostředí
Ústav chemie materiálů