Surface Analyses of PVDF/NMP/[EMIM][TFSI] Solid Polymer Electrolyte

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dc.contributor.authorSedlák, Petrcs
dc.contributor.authorSobola, Dinaracs
dc.contributor.authorGajdoš, Adamcs
dc.contributor.authorDallaev, Rashidcs
dc.contributor.authorNebojsa, Aloiscs
dc.contributor.authorKuberský, Petrcs
dc.coverage.issue16cs
dc.coverage.volume13cs
dc.date.accessioned2021-11-12T23:56:58Z
dc.date.available2021-11-12T23:56:58Z
dc.date.issued2021-08-11cs
dc.description.abstractThermal treatment conditions of solid polymer polymer electrolyte (SPE) were studied with respect to their impact on the surface morphology, phase composition and chemical composition of an imidazolium ionic-liquid-based SPE, namely PVDF/NMP/[EMIM][TFSI] electrolyte. These investigations were done using scanning electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, differential scanning calorimetry as well as X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectroscopy. A thoroughly mixed blend of polymer matrix, ionic liquid and solvent was deposited on a ceramic substrate and was kept at a certain temperature for a specific time in order to achieve varying crystallinity. The morphology of all the electrolytes consists of spherulites whose average diameter increases with solvent evaporation rate. Raman mapping shows that these spherulites have a semicrystalline structure and the area between them is an amorphous region. Analysis of FTIR spectra as well as Raman spectroscopy showed that the -phase becomes dominant over other phases, while DSC technique indicated decrease of crystallinity as the solvent evaporation rate increases. XPS and ToF-SIMS indicated that the chemical composition of the surface of the SPE samples with the highest solvent evaporation rate approaches the composition of the ionic liquid.en
dc.formattextcs
dc.format.extent1-16cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationPolymers. 2021, vol. 13, issue 16, p. 1-16.en
dc.identifier.doi10.3390/polym13162678cs
dc.identifier.issn2073-4360cs
dc.identifier.other172231cs
dc.identifier.urihttp://hdl.handle.net/11012/201005
dc.language.isoencs
dc.publisherMDPIcs
dc.relation.ispartofPolymerscs
dc.relation.urihttps://www.mdpi.com/2073-4360/13/16/2678cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/2073-4360/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectsolid polymer electrolyteen
dc.subjectimidazolium ionic liquidsen
dc.subjectpoly-(vinylidene fluoride)en
dc.subjectcrystallinityen
dc.subjectsolvent evaporationen
dc.subjectRaman spectroscopyen
dc.subjectFourier transform infrared spectroscopyen
dc.subjectX-ray photoelectron spectroscopyen
dc.subjectsecondary ion mass spectroscopyen
dc.titleSurface Analyses of PVDF/NMP/[EMIM][TFSI] Solid Polymer Electrolyteen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-172231en
sync.item.dbtypeVAVen
sync.item.insts2022.01.11 12:54:34en
sync.item.modts2022.01.11 12:15:26en
thesis.grantorVysoké učení technické v Brně. Fakulta elektrotechniky a komunikačních technologií. Ústav fyzikycs
thesis.grantorVysoké učení technické v Brně. Středoevropský technologický institut VUT. Sdílená laboratoř RP1cs
thesis.grantorVysoké učení technické v Brně. Středoevropský technologický institut VUT. Pokročilé keramické materiálycs
thesis.grantorVysoké učení technické v Brně. Fakulta strojního inženýrství. Ústav fyzikálního inženýrstvícs
thesis.grantorVysoké učení technické v Brně. Středoevropský technologický institut VUT. Pokročilé instrumentace a metody pro charakterizace materiálůcs
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Pokročilé instrumentace a metody pro charakterizace materiálů
Pokročilé keramické materiály
Sdílená laboratoř RP1
Ústav fyziky
Ústav fyzikálního inženýrství