Novel Riboflavin-Inspired Conjugated Bio-Organic Semiconductors

dc.contributor.authorRichtár, Jancs
dc.contributor.authorHeinrichová, Patriciecs
dc.contributor.authorApaydin, Dogukan Hazarcs
dc.contributor.authorSchmiedová, Veronikacs
dc.contributor.authorYumusak, Cigdemcs
dc.contributor.authorKovalenko, Alexandercs
dc.contributor.authorWeiter, Martincs
dc.contributor.authorSariciftci, N.S.cs
dc.contributor.authorKrajčovič, Jozefcs
dc.coverage.issue23cs
dc.coverage.volume2018cs
dc.date.issued2018-09-05cs
dc.description.abstractFlavins are known to be extremely versatile, thus enabling routes to innumerable modifications in order to obtain desired properties. Thus, in the present paper, the group of bio-inspired conjugated materials based on the alloxazine core is synthetized using two efficient novel synthetic approaches providing relatively high reaction yields. The comprehensive characterization of the materials, in order to evaluate the properties and application potential, has shown that the modification of the initial alloxazine core with aromatic substituents allows fine tuning of the optical bandgap, position of electronic orbitals, absorption and emission properties. Interestingly, the compounds possess multichromophoric behavior, which is assumed to be the results of an intramolecular proton transfer.en
dc.formattextcs
dc.format.extent2271-2289cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationMOLECULES. 2018, vol. 2018, issue 23, p. 2271-2289.en
dc.identifier.doi10.3390/molecules23092271cs
dc.identifier.issn1420-3049cs
dc.identifier.orcid0000-0003-1422-9917cs
dc.identifier.orcid0000-0001-7886-8588cs
dc.identifier.orcid0000-0002-7495-1787cs
dc.identifier.other149690cs
dc.identifier.urihttp://hdl.handle.net/11012/137082
dc.language.isoencs
dc.publisherMDPIcs
dc.relation.ispartofMOLECULEScs
dc.relation.urihttp://www.mdpi.com/1420-3049/23/9/2271cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/1420-3049/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectbio-inspired materialen
dc.subjectconjugated materialsen
dc.subjectflavinsen
dc.subjectbiomimetic energy storageen
dc.subjectoxygen evolutionen
dc.titleNovel Riboflavin-Inspired Conjugated Bio-Organic Semiconductorsen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-149690en
sync.item.dbtypeVAVen
sync.item.insts2025.02.03 15:37:53en
sync.item.modts2025.01.17 15:13:16en
thesis.grantorVysoké učení technické v Brně. Fakulta chemická. Ústav chemie a technologie ochrany životního prostředícs
thesis.grantorVysoké učení technické v Brně. Fakulta chemická. Centrum materiálového výzkumucs
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