Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity

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dc.contributor.authorKopel, Pavelcs
dc.contributor.authorDoležal, Karelcs
dc.contributor.authorLanger, Vratislavcs
dc.contributor.authorJun, Danielcs
dc.contributor.authorAdam, Vojtěchcs
dc.contributor.authorKuča, Kamilcs
dc.contributor.authorKizek, Renécs
dc.coverage.issue4cs
dc.coverage.volume19cs
dc.date.accessioned2020-08-04T11:04:01Z
dc.date.available2020-08-04T11:04:01Z
dc.date.issued2014-04-08cs
dc.description.abstractThe complexes of Fe(II), Mn(II) and Ni(II) with a combination of a Schiff base, nitrogen-donor ligand or macrocyclic ligand and trithiocyanuric acid (ttcH3) were prepared and characterized by elemental analysis and spectroscopies. Crystal and molecular structures of the iron complex of composition [Fe(L1)](ttcH2)(ClO4) EtOH H2O (1), where L1 is Schiff base derived from tris(2-aminoethyl)amine and 2-pyridinecarboxaldehyde, were solved. It was found that the Schiff base is coordinated to the central iron atom by six nitrogens forming deformed octahedral arrangement, whereas trithiocyanurate(1-) anion, perchlorate and solvent molecules are not coordinated. The X-ray structure of the Schiff base sodium salt is also presented and compared with the iron complex. The anticholinesterase activity of the complexes was also studied.en
dc.description.abstractKomplexy Fe (II), Mn (II) a Ni (II), s kombinací Schiffovy bází, dárce dusíku ligand nebo makrocyclický ligand a kyselina trithiocyanuric (ttcH3) byly připraveny a charakterizovány pomocí elementární analýzy a spektroskopie.Byly zde řešeny krystaly a molekulární struktury komplexu železa o složení [Fe (L1)] (ttcH2) (ClO 4) EtOH H 2O (1), kde L1 je Schiffovy báze odvozené od tris (2-aminoethyl) amin a 2-pyridinkarboxaldehydu. Bylo zjištěno, že Schiffova báze je koordinována na centrálním atomu železa šesti atomy dusíku tvořenou deformovanou osmibokou přípravou, zatímco trithiocyanurate (1) aniontu,chloristanové a molekuly rozpouštědla nejsou koordinovány.X-ray struktura Schiff na bázi solného sodíků jsou prezentovány ve srovnání s komplexy železa. Byly také studovány Inhibitory aktivita komplexů.cs
dc.formattextcs
dc.format.extent4338-4354cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationMOLECULES. 2014, vol. 19, issue 4, p. 4338-4354.en
dc.identifier.doi10.3390/molecules19044338cs
dc.identifier.issn1420-3049cs
dc.identifier.other109374cs
dc.identifier.urihttp://hdl.handle.net/11012/63717
dc.language.isoencs
dc.publisherMDPIcs
dc.relation.ispartofMOLECULEScs
dc.relation.urihttp://www.mdpi.com/1420-3049/19/4/4338cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/1420-3049/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectkyselina trithiocyanuric
dc.subjecttrimercaptotriazine
dc.subjectkrystalová struktura
dc.subjectkomplexy
dc.subjectacetylcholinesterázní činnosti
dc.subjectSchiff base
dc.subjecttrithiocyanuric aciden
dc.subjecttrimercaptotriazineen
dc.subjectcrystal structureen
dc.subjectcomplexesen
dc.subjectacetylcholinesterase activityen
dc.subjectSchiff baseen
dc.titleTrithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activityen
dc.title.alternativeTrithiocyanurate omplexy železa, manganu a niklu a jejich anticholinesterázní činnostics
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-109374en
sync.item.dbtypeVAVen
sync.item.insts2020.08.04 13:04:01en
sync.item.modts2020.08.04 12:45:33en
thesis.grantorVysoké učení technické v Brně. Středoevropský technologický institut VUT. Chytré nanonástrojecs
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