Electrocatalytic activity of layered MAX phases for the hydrogen evolution reaction

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dc.contributor.authorKandambath Padinjareveetil, Akshay Kumarcs
dc.contributor.authorAlduhaish, Osamahcs
dc.contributor.authorPumera, Martincs
dc.coverage.issue1cs
dc.coverage.volume125cs
dc.date.issued2021-04-01cs
dc.description.abstractThe hydrogen evolution reaction (HER) is important for the advancement of next-generation electrochemical energy devices. The search for an alternative inexpensive catalyst for energy conversion to replace expensive and rare noble metals is of high priority. There has been a significant push to investigate electrocatalysis of various layered materials for hydrogen evolution. However, the electrocatalytic activity of layered MAX phases remains largely unexplored. Herein, electrocatalytic activity studies of MAX (Ti2AlC, Ta2AlC, Ti2SnC, Ti3SiC2, V2AlC, Mo2TiAlC2, and Cr2AlC) phases are conducted. Material and electrochemical characterization are carried out to understand the morphology and catalytic activity, respectively. From Tafel slope analysis, it was found that proton adsorption is the rate-limiting step for all the MAX phases studied. Double transition-metal MAX carbides (Mo2TiAlC2) showed better catalytic activity for HER than single transition-metal MAX carbides.en
dc.formattextcs
dc.format.extent1-4cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationELECTROCHEMISTRY COMMUNICATIONS. 2021, vol. 125, issue 1, p. 1-4.en
dc.identifier.doi10.1016/j.elecom.2021.106977cs
dc.identifier.issn1388-2481cs
dc.identifier.orcid0000-0001-5846-2951cs
dc.identifier.other171388cs
dc.identifier.researcheridF-2724-2010cs
dc.identifier.urihttp://hdl.handle.net/11012/196788
dc.language.isoencs
dc.publisherElseviercs
dc.relation.ispartofELECTROCHEMISTRY COMMUNICATIONScs
dc.relation.urihttps://www.sciencedirect.com/science/article/pii/S1388248121000618cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/1388-2481/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectMAX phasesen
dc.subjectLayered materialsen
dc.subjectDouble transition MAX carbidesen
dc.subjectElectrochemistryen
dc.subjectHydrogen evolution reactionen
dc.titleElectrocatalytic activity of layered MAX phases for the hydrogen evolution reactionen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-171388en
sync.item.dbtypeVAVen
sync.item.insts2025.02.03 15:50:29en
sync.item.modts2025.01.17 16:33:16en
thesis.grantorVysoké učení technické v Brně. Středoevropský technologický institut VUT. Energie budoucnosti a inovacecs
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