Temperature effect on the kinetic profile of Ziegler-Natta catalyst in propene polymerization

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dc.contributor.authorKolomazník, Vítcs
dc.contributor.authorCejpek, Igorcs
dc.contributor.authorSkoumal, Miroslavcs
dc.coverage.issue15cs
dc.coverage.volume78cs
dc.date.accessioned2025-04-04T11:56:15Z
dc.date.available2025-04-04T11:56:15Z
dc.date.issued2024-09-10cs
dc.description.abstractPropene polymerization kinetic profiles with a diether-based Ziegler-Natta MgCl2-supported catalyst were investigated in a stainless-steel batch reactor. The initial 10 min period characterizes various temperature levels with a constant volume of liquid propene. The lowest temperature level corresponds to the usual prepolymerization temperature (10 degrees C), and the highest level corresponds to the usual main polymerization temperature (70 degrees C). The effects of the starting temperature levels were evaluated through polymerization kinetic patterns computed namely from the second polymerization period carried out at 70 degrees C for the next 90 min. Based on the heat transfer data, the kinetic profiles were fitted to suitable semi-empirical equations derived from fundamental kinetic approaches using the first and second orders of the catalyst active sites decay. Both approaches adequately describe the dependence of the initial activities and deceleration constants on the temperature during the initial period.en
dc.formattextcs
dc.format.extent8397-8408cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationCHEMICAL PAPERS. 2024, vol. 78, issue 15, p. 8397-8408.en
dc.identifier.doi10.1007/s11696-024-03679-wcs
dc.identifier.issn2585-7290cs
dc.identifier.orcid0000-0003-1838-173Xcs
dc.identifier.other197238cs
dc.identifier.urihttps://hdl.handle.net/11012/250716
dc.language.isoencs
dc.publisherSPringer Naturecs
dc.relation.ispartofCHEMICAL PAPERScs
dc.relation.urihttps://link.springer.com/article/10.1007/s11696-024-03679-wcs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/2585-7290/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectPropene polymerizationen
dc.subjectZiegler-Natta catalysten
dc.subjectPolymerization kineticsen
dc.subjectEffect of temperatureen
dc.subjectBatch reactoren
dc.subjectSecond order of decelerationen
dc.titleTemperature effect on the kinetic profile of Ziegler-Natta catalyst in propene polymerizationen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-197238en
sync.item.dbtypeVAVen
sync.item.insts2025.04.04 13:56:15en
sync.item.modts2025.03.31 08:32:04en
thesis.grantorVysoké učení technické v Brně. Fakulta chemická. Centrum materiálového výzkumucs
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