Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

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dc.contributor.authorNemec, Ivancs
dc.contributor.authorSvoboda, Ingridcs
dc.contributor.authorHerchel, Radovancs
dc.coverage.issue8cs
dc.coverage.volume9cs
dc.date.issued2019-08-02cs
dc.description.abstractThe synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA(2-) is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations.en
dc.description.abstractThe synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA(2-) is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations.en
dc.formattextcs
dc.format.extent1-11cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationMetals. 2019, vol. 9, issue 8, p. 1-11.en
dc.identifier.doi10.3390/met9080849cs
dc.identifier.issn2075-4701cs
dc.identifier.orcid0000-0003-3231-7849cs
dc.identifier.other157945cs
dc.identifier.researcheridA-6969-2010cs
dc.identifier.scopus57201282084cs
dc.identifier.urihttp://hdl.handle.net/11012/194809
dc.language.isoencs
dc.publisherMDPIcs
dc.relation.ispartofMetalscs
dc.relation.urihttps://www.mdpi.com/2075-4701/9/8/849cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/2075-4701/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectspin crossoveren
dc.subjectSchiff base ligandsen
dc.subjectiron (III) complexen
dc.subjectstructureen
dc.subjectmagnetismen
dc.subjectspin crossover
dc.subjectSchiff base ligands
dc.subjectiron (III) complex
dc.subjectstructure
dc.subjectmagnetism
dc.titleSpin Crossover in Three Mononuclear Iron (III) Schiff Base Complexesen
dc.title.alternativeSpin Crossover in Three Mononuclear Iron (III) Schiff Base Complexesen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-157945en
sync.item.dbtypeVAVen
sync.item.insts2025.10.14 15:17:59en
sync.item.modts2025.10.14 10:10:03en
thesis.grantorVysoké učení technické v Brně. Středoevropský technologický institut VUT. Magneto-Optická a THz Spektroskopiecs

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