Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

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metals0900849.pdf(1.49 MB)
Date
2019-08-02
Authors
Nemec, Ivan
Svoboda, Ingrid
Herchel, Radovan
ORCID
0000-0003-3231-7849
Advisor
Referee
Mark
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Volume Title
Publisher
MDPI
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Abstract
The synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA(2-) is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations.
Description
Keywords
spin crossover, Schiff base ligands, iron (III) complex, structure, magnetism
Citation
Metals. 2019, vol. 9, issue 8, p. 1-11.
https://www.mdpi.com/2075-4701/9/8/849
Document type
Peer-reviewed
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Published version
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Language of document
en
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Defence
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Document licence
Creative Commons Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
DOI
10.3390/met9080849
URI
http://hdl.handle.net/11012/194809
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Magneto-Optická a THz Spektroskopie
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