This manuscript presents a comprehensive exploration of the band gap structure in (CoCrFeNiMn)3O4 powders through a series of experimental investigations. The combined use of optical techniques, and X-ray photoelectron spectroscopy in this study offers a comprehensive characterization of the band gap structure in (CoCrFeNiMn)3O4 powders. The findings contribute to the understanding of the material's electronic properties and pave the way for potential applications in electronic and optical devices.