Novel Trinuclear Copper(II) Complex: Crystal Structure at 100 K and Magnetic Properties of (R, S)-di[(6,7-dimethoxy-isoquinolin-1-yl)-(3,4-dimethoxy-phenyl)-methanolato]-tetra(2-hydroxybenzoato)-diaqua-tricopper dihydrate, [Cu3(C7H5O3)4(C20H20NO5)2(H2O)2]<middle dot>2(H2O)
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Date
2024-06-01
Authors
Valach, Fedor
Pavlik, Ján
Šalitroš, Ivan
Melník, Milan
Kožíšek, Jozef
ORCID
0000-0003-3856-0399Advisor
Referee
Mark
Journal Title
Journal ISSN
Volume Title
Publisher
SPRINGER/PLENUM PUBLISHERS
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Abstract
The crystal structure of [Cu-3(C7H5O3)(4)(C20H20NO5)(2)(H2O)(2)]2(H2O) (1) and analysis of temperature and field dependence of magnetic susceptibility is reported in this work. The structure of 1 is composed of trinuclear complex units and water molecules. The middle copper atom occupies the center of symmetry. N, O-bonded (6,7-dimethoxy-isoquinolin-1-yl)-(3,4-dimethoxy-phenyl)-methanolato ligands, 2-hydroxybenzoates with bridging carboxylic groups, and oxo-bridged water molecules connect the middle Cu(II) atom with the terminal copper atoms. Two 2-hydroxybenzoates coordinate the terminal copper atoms via one carboxylic oxygen and an O atom of the hydroxyl group. The analysis of copper coordination by bond-valence sum approach and relevant structural correlation is consistent with hexacoordinated Cu(II) centers. CuCu separation is 3.0269(3) & Aring;. The magnetism of 1 shows a strong ferromagnetic interaction between the neighboring metallic centers accompanied by very weak antiferromagnetic intermolecular interactions. The complex units are mutually held by pipi stack interactions of 2-hydroxybenzoates and hydrogen bonds.
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Citation
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY. 2024, vol. 54, issue 2, p. 163-172.
https://link.springer.com/article/10.1007/s10870-024-01009-2
https://link.springer.com/article/10.1007/s10870-024-01009-2
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Peer-reviewed
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en