The effect of thermal treatment on ac/dc conductivity and current fluctuations of PVDF/NMP/[EMIM][TFSI] solid polymer electrolyte

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dc.contributor.authorSedlák, Petrcs
dc.contributor.authorGajdoš, Adamcs
dc.contributor.authorMacků, Robertcs
dc.contributor.authorMajzner, Jiřícs
dc.contributor.authorHolcman, Vladimírcs
dc.contributor.authorSedláková, Vlastacs
dc.contributor.authorKuberský, Petrcs
dc.coverage.issue1cs
dc.coverage.volume10cs
dc.date.issued2020-12-03cs
dc.description.abstractThe experimental study deals with the investigation of the effect of diverse crystallinity of imidazolium ionic-liquid-based SPE on conductivity and current fluctuations. The experimental study was carried out on samples consisting of [EMIM][TFSI] as ionic liquid, PVDF as a polymer matrix and NMP as a solvent. After the deposition, the particular sample was kept at an appropriate temperature for a specific time in order to achieve different crystalline forms of the polymer in the solvent, since the solvent evaporation rate controls crystallization. The ac/dc conductivities of SPEs were investigated across a range of temperatures using broadband dielectric spectroscopy in terms of electrical conductivity. In SPE samples of the higher solvent evaporation rate, the real parts of conductivity spectra exhibit a sharper transition during sample cooling and an increase of overall conductivity, which is implied by a growing fraction of the amorphous phase in the polymer matrix in which the ionic liquid is immobilized. The conductivity master curves illustrate that the changing of SPEs morphology is reflected in the low frequency regions governed by the electrode polarization effect. The dc conductivity of SPEs exhibits Vogel-Fulcher-Tammann temperature dependence and increases with the intensity of thermal treatment. Spectral densities of current fluctuations showed that flicker noise, thermal noise and shot noise seems to be major noise sources in all samples. The increase of electrolyte conductivity causes a decrease in bulk resistance and partially a decrease in charge transfer resistance, while also resulting in an increase in shot noise. However, the change of electrode material results in a more significant change of spectral density of current fluctuations than the modification of the preparation condition of the solid polymer electrolyte. Thus, the contact noise is considered to contribute to overall current fluctuations across the samples.en
dc.formattextcs
dc.format.extent1-12cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationScientific Reports. 2020, vol. 10, issue 1, p. 1-12.en
dc.identifier.doi10.1038/s41598-020-78363-6cs
dc.identifier.issn2045-2322cs
dc.identifier.orcid0000-0003-2454-7951cs
dc.identifier.orcid0000-0001-9220-5510cs
dc.identifier.orcid0000-0002-0811-2432cs
dc.identifier.orcid0000-0003-3971-9939cs
dc.identifier.orcid0000-0001-7402-4660cs
dc.identifier.orcid0000-0002-4151-7714cs
dc.identifier.other166312cs
dc.identifier.researcheridE-2354-2012cs
dc.identifier.researcheridAAH-3686-2019cs
dc.identifier.researcheridE-2382-2012cs
dc.identifier.researcheridE-2452-2012cs
dc.identifier.researcheridE-2366-2012cs
dc.identifier.researcheridE-2453-2012cs
dc.identifier.scopus57201044717cs
dc.identifier.scopus57195423059cs
dc.identifier.scopus23767216400cs
dc.identifier.scopus24178886700cs
dc.identifier.scopus25928429400cs
dc.identifier.scopus6508143154cs
dc.identifier.urihttp://hdl.handle.net/11012/195854
dc.language.isoencs
dc.publisherNATURE RESEARCHcs
dc.relation.ispartofScientific Reportscs
dc.relation.urihttps://www.nature.com/articles/s41598-020-78363-6cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/2045-2322/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectsolid polymer electrolyteen
dc.subjectcurrent fluctuationsen
dc.subjectPoly(vinylidene fluoride)en
dc.subjectimidazolium ionic liquiden
dc.subjectsolvent evaporation temperatureen
dc.subjectconductivityen
dc.subjectVogel-Fulcher-Tammann dependenceen
dc.subjectinterdigital electrode.en
dc.titleThe effect of thermal treatment on ac/dc conductivity and current fluctuations of PVDF/NMP/[EMIM][TFSI] solid polymer electrolyteen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-166312en
sync.item.dbtypeVAVen
sync.item.insts2025.02.03 15:40:25en
sync.item.modts2025.01.17 15:13:01en
thesis.grantorVysoké učení technické v Brně. Fakulta elektrotechniky a komunikačních technologií. Ústav fyzikycs
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