Thermodynamic Analysis of the Landolt-Type Autocatalytic System

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dc.contributor.authorPekař, Miloslavcs
dc.coverage.issue11cs
dc.coverage.volume11cs
dc.date.accessioned2021-10-30T14:54:27Z
dc.date.available2021-10-30T14:54:27Z
dc.date.issued2021-10-28cs
dc.description.abstractA recent work demonstrated on the example of the Landolt-type reaction system how the simplest autocatalytic loop is described by the kinetic mass action law and proper parametrization of direct and autocatalytic pathways. Using a methodology of non-equilibrium thermodynamics the thermodynamic consistency of that kinetic model is analyzed and the mass action description generalized including an alternative description by the empirical rate equation. Relationships between independent and dependent reactions and their rates are given. The mathematical modeling shows that following the time evolution of reaction rates provides additional insight into autocatalytic behavior. A brief note on thermodynamic driving forces and coupling with diffusion is added. In summary, this work extends and generalizes the kinetic description of the Landolt-type system placing it within the framework of non-equilibrium thermodynamics and demonstrating its thermodynamic consistency.en
dc.formattextcs
dc.format.extent1-11cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationCatalysts. 2021, vol. 11, issue 11, p. 1-11.en
dc.identifier.doi10.3390/catal11111300cs
dc.identifier.issn2073-4344cs
dc.identifier.other172950cs
dc.identifier.urihttp://hdl.handle.net/11012/201795
dc.language.isoencs
dc.publisherMDPIcs
dc.relation.ispartofCatalystscs
dc.relation.urihttps://www.mdpi.com/2073-4344/11/11/1300cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/2073-4344/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectautocatalysis; Landolt reactionen
dc.subjectnon-equilibrium thermodynamicsen
dc.subjectreaction rateen
dc.subjectthermodynamic consistencyen
dc.titleThermodynamic Analysis of the Landolt-Type Autocatalytic Systemen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-172950en
sync.item.dbtypeVAVen
sync.item.insts2021.12.15 16:55:15en
sync.item.modts2021.12.15 16:15:05en
thesis.grantorVysoké učení technické v Brně. Fakulta chemická. Ústav fyzikální a spotřební chemiecs
thesis.grantorVysoké učení technické v Brně. Fakulta chemická. CMV laboratoř biokoloidůcs
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