Conversion of novel non-edible Bischofia javanica seed oil into methyl ester via recyclable zirconia-based phyto-nanocatalyst: A circular bioeconomy approach for eco-sustenance

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dc.contributor.authorAmeen, Mariacs
dc.contributor.authorZafar, Muhammadcs
dc.contributor.authorRamadan, Mohamed Fawzycs
dc.contributor.authorAhmad, Mushtaqcs
dc.contributor.authorMakhkamov, Trobjoncs
dc.contributor.authorBokhari, Syed Awais Ali Shahcs
dc.contributor.authorMubashir, Muhammadcs
dc.contributor.authorChuah, Lai Fattcs
dc.contributor.authorShow, Pau Lokecs
dc.coverage.issue1cs
dc.coverage.volume30cs
dc.date.issued2023-05-01cs
dc.description.abstractThe current study assesses Bischofia javanica Blume's potential as novel non-edible seed oil for environmentally benign biodiesel production using phyto-nanocatalyst, i.e., green nanoparticles (NPs) of zirconium oxide (ZrO2) synthesized with aqueous leaf extract of the same plant via the biological method. Using response surface methods, the maximum yield (95.8 wt.%) was obtained at a 1:6 oil-to-methanol molar ratio, 2.5 wt.% catalyst loading, 70 degrees C reaction temperature and 2 h of reaction time. In addition, advanced analytical techniques such as Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) were used to characterize green nanoparticles. Six peaks in the GC-MS spectrum were identified, showing the presence of six different methyl esters such as methyl palmitate, methyl linoleate, methyl oleate, methyl stearate, methyl linolenate and methyl 11-eicosenoate. In addition, 1HNMR and 13CNMR confirmed the high conversion yield of the esters group with distinct peaks at 3.649 ppm and 174.19 ppm. Biodiesel prepared from Bischofia javanica has fuel qualities that meet international standards. Fuel properties were found analogous to international standards viz. ASTM and EN. These include flash point (80 degrees C), density at 15 degrees C (0.8623 kg/L), kinematic viscosity (5.32 mm2/s), cloud (-11 degrees C), pour point (-8 degrees C) and sulphur content of 0.00047 wt.%. The results indicate that the green nanocatalyst and synthesized biodiesel from the Bischofia javanica appear to be highly reliable and cost-effective candidates for producing sustainable and eco-friendly biodiesel to overcome energy crises and climatic deteriorations, which would assist in the shift from a linear to a circular economy.(c) 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).en
dc.formattextcs
dc.format.extent1-17cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationEnvironmental Technology and Innovation. 2023, vol. 30, issue 1, p. 1-17.en
dc.identifier.doi10.1016/j.eti.2023.103101cs
dc.identifier.issn2352-1864cs
dc.identifier.orcid0000-0002-0748-6336cs
dc.identifier.other187268cs
dc.identifier.researcheridABF-6997-2020cs
dc.identifier.scopus55251309900cs
dc.identifier.urihttp://hdl.handle.net/11012/244937
dc.language.isoencs
dc.publisherElseviercs
dc.relation.ispartofEnvironmental Technology and Innovationcs
dc.relation.urihttps://www.sciencedirect.com/science/article/pii/S2352186423000974cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/2352-1864/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectGreen synthesisen
dc.subjectSeed oilen
dc.subjectBiofuelen
dc.subjectBiodieselen
dc.subjectPhyto-nanocatalysten
dc.subjectEco-sustenanceen
dc.subjectCircular economyen
dc.subjectWASTE COOKING OILen
dc.subjectHYDRODYNAMIC CAVITATIONen
dc.subjectPERFORMANCEen
dc.titleConversion of novel non-edible Bischofia javanica seed oil into methyl ester via recyclable zirconia-based phyto-nanocatalyst: A circular bioeconomy approach for eco-sustenanceen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-187268en
sync.item.dbtypeVAVen
sync.item.insts2025.02.03 15:47:20en
sync.item.modts2025.01.17 18:41:48en
thesis.grantorVysoké učení technické v Brně. Fakulta strojního inženýrství. Laboratoř integrace procesůcs
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