Variation of Spin-Transition Temperature in the Iron(III) Complex Induced by Different Compositions of the Crystallization Solvent

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dc.contributor.authorNemec, Ivancs
dc.contributor.authorKotásková, Luciecs
dc.contributor.authorHerchel, Radovancs
dc.coverage.issue3cs
dc.coverage.volume23cs
dc.date.accessioned2024-01-19T20:38:41Z
dc.date.available2024-01-19T20:38:41Z
dc.date.issued2023-03-01cs
dc.description.abstractWe crystallized the Schiff-base iron(III) spin-crossover complex [Fe(3,5Cl-L5)(NCSe)] from different two-component solvent mixtures containing methanol and chloroform (phi = V(CH3OH)/V(solvent) = 0.05, 0.25, 0.50, 0.83, and 1.00). The obtained crystalline products were characterized by X-ray diffraction, and it was confirmed that they are all composed of the same crystalline phase, and they do not contain any crystal solvent. However, significant differences in magnetic properties were observed, and thermal hysteresis changed from (in K) 121T down arrow and 134T up arrow for phi = 0.05 and 0.25, down to 72T down arrow and 96T up arrow for phi = 1.00. The crystal structures of the low-spin and high-spin phases were studied theoretically and experimentally.en
dc.formattextcs
dc.format.extent1323-1329cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationCrystal Growth and Design. 2023, vol. 23, issue 3, p. 1323-1329.en
dc.identifier.doi10.1021/acs.cgd.2c01411cs
dc.identifier.issn1528-7505cs
dc.identifier.orcid0000-0003-3231-7849cs
dc.identifier.orcid0000-0003-4825-3616cs
dc.identifier.other184146cs
dc.identifier.researcheridA-6969-2010cs
dc.identifier.scopus57201282084cs
dc.identifier.urihttps://hdl.handle.net/11012/244306
dc.language.isoencs
dc.publisherAmerican Chemical Societycs
dc.relation.ispartofCrystal Growth and Designcs
dc.relation.urihttps://pubs.acs.org/doi/10.1021/acs.cgd.2c01411cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/1528-7505/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectCrystal structureen
dc.subjectCrystallizationen
dc.subjectCrystalsen
dc.subjectDiffractionen
dc.subjectSolventsen
dc.titleVariation of Spin-Transition Temperature in the Iron(III) Complex Induced by Different Compositions of the Crystallization Solventen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-184146en
sync.item.dbtypeVAVen
sync.item.insts2024.01.19 21:38:41en
sync.item.modts2024.01.16 12:12:39en
thesis.grantorVysoké učení technické v Brně. Středoevropský technologický institut VUT. Magneto-Optická a THz Spektroskopiecs
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