Macroscopic derivation of the kinetic mass-action law

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dc.contributor.authorPekař, Miloslavcs
dc.coverage.issue1cs
dc.coverage.volume99cs
dc.date.issued2010-01-01cs
dc.description.abstractUsing several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.en
dc.description.abstractOdvození kinetického zákona o působení hmoty metodami nerovnážné termodynamiky kontinua, zavedení nového pojmu termodynamický polynom do kinetiky.cs
dc.formattextcs
dc.format.extent29-35cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationReaction Kinetics, Mechanisms and Catalysis. 2010, vol. 99, issue 1, p. 29-35.en
dc.identifier.doi10.1007/s11144-009-0101-6cs
dc.identifier.issn1878-5190cs
dc.identifier.orcid0000-0002-3878-0917cs
dc.identifier.other48539cs
dc.identifier.urihttp://hdl.handle.net/11012/19701
dc.language.isoencs
dc.publisherSpringer-Verlagcs
dc.relation.ispartofReaction Kinetics, Mechanisms and Catalysiscs
dc.relation.urihttp://link.springer.com/10.1007/s11144-009-0101-6cs
dc.rights(C) Springer-Verlagcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/1878-5190/cs
dc.subjectmass actionen
dc.subjectreaction rateen
dc.subjectthermodynamic polynomialen
dc.subjectthermodynamicsen
dc.subjectkinetika
dc.subjectreakční rychlost
dc.subjecttermodynamický polynom
dc.subjecttermodynamika
dc.subjectzákon o působení hmoty
dc.titleMacroscopic derivation of the kinetic mass-action lawen
dc.title.alternativeMakroskopické odvození zákona o působení hmoty v kineticecs
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionacceptedVersionen
sync.item.dbidVAV-48539en
sync.item.dbtypeVAVen
sync.item.insts2025.02.03 15:38:52en
sync.item.modts2025.01.17 20:32:29en
thesis.grantorVysoké učení technické v Brně. Fakulta chemická. Ústav fyzikální a spotřební chemiecs
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