Macroscopic derivation of the kinetic mass-action law

Simple item page
dc.contributor.authorPekař, Miloslavcs
dc.coverage.issue1cs
dc.coverage.volume99cs
dc.date.issued2010-01-01cs
dc.description.abstractUsing several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.en
dc.description.abstractUsing several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.en
dc.formattextcs
dc.format.extent29-35cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationReaction Kinetics Mechanisms and Catalysis. 2010, vol. 99, issue 1, p. 29-35.en
dc.identifier.doi10.1007/s11144-009-0101-6cs
dc.identifier.issn1878-5190cs
dc.identifier.orcid0000-0002-3878-0917cs
dc.identifier.other48539cs
dc.identifier.urihttp://hdl.handle.net/11012/19701
dc.language.isoencs
dc.publisherSpringer-Verlagcs
dc.relation.ispartofReaction Kinetics Mechanisms and Catalysiscs
dc.relation.urihttp://link.springer.com/10.1007/s11144-009-0101-6cs
dc.rights(C) Springer-Verlagcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/1878-5190/cs
dc.subjectmass actionen
dc.subjectreaction rateen
dc.subjectthermodynamic polynomialen
dc.subjectthermodynamicsen
dc.subjectmass action
dc.subjectreaction rate
dc.subjectthermodynamic polynomial
dc.subjectthermodynamics
dc.titleMacroscopic derivation of the kinetic mass-action lawen
dc.title.alternativeMacroscopic derivation of the kinetic mass-action lawen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionacceptedVersionen
sync.item.dbidVAV-48539en
sync.item.dbtypeVAVen
sync.item.insts2025.10.14 14:07:58en
sync.item.modts2025.10.14 10:13:08en
thesis.grantorVysoké učení technické v Brně. Fakulta chemická. Ústav fyzikální a spotřební chemiecs

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
Macroscopic derivation of the kinetic massaction law.pdf
Size:
126.13 KB
Format:
Adobe Portable Document Format
Description:
Macroscopic derivation of the kinetic massaction law.pdf
Download

Collections

Ústav fyzikální a spotřební chemie