Co(II)-Based single-ion magnets with 1,1 '-ferrocenediyl-bis(diphenylphosphine) metalloligands

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dc.contributor.authorHrubý, Jakubcs
dc.contributor.authorDvořák, Daliborcs
dc.contributor.authorSquillantini, Lorenzocs
dc.contributor.authorMannini, Mateocs
dc.contributor.authorvan Slageren, Joriscs
dc.contributor.authorHerchel, Radovancs
dc.contributor.authorNemec, Ivancs
dc.contributor.authorNeugebauer, Petrcs
dc.coverage.issue33cs
dc.coverage.volume49cs
dc.date.issued2020-09-07cs
dc.description.abstractHerein, we report on investigations of magnetic and spectroscopic properties of three heterobimetallic Fe(ii)-Co(ii) coordination compounds based on the tetracoordinate {CoP2X2} core encapsulated by dppf metalloligand, where X = Cl (1), Br (2), I (3), dppf = 1,1 '-ferrocenediyl -bis(diphenylphosphine). The analysis of static magnetic data has revealed the presence of axial magnetic anisotropy in compounds (1) and (2) and this was further confirmed by high-frequency electron spin resonance (HF-ESR) spectroscopy. Dynamic magnetic data confirmed that (1) and (2) behave as field-induced Single-Ion Magnets (SIMs). Together with bulk studies, we have also tested the possibility of depositing (2) as thick films on Au(111), glass, and polymeric acetate by drop-casting as well as thermal sublimation, a key aspect for the development of future devices embedding these magnetic objects.en
dc.formattextcs
dc.format.extent11697-11707cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationDalton Transactions. 2020, vol. 49, issue 33, p. 11697-11707.en
dc.identifier.doi10.1039/d0dt01512acs
dc.identifier.issn1477-9234cs
dc.identifier.orcid0000-0003-4947-3688cs
dc.identifier.orcid0000-0003-3231-7849cs
dc.identifier.orcid0000-0001-7095-6401cs
dc.identifier.other165497cs
dc.identifier.researcheridO-3974-2017cs
dc.identifier.researcheridA-6969-2010cs
dc.identifier.researcheridI-7844-2013cs
dc.identifier.scopus57201282084cs
dc.identifier.urihttp://hdl.handle.net/11012/195858
dc.language.isoencs
dc.publisherRoyal Society of Chemistrycs
dc.relation.ispartofDalton Transactionscs
dc.relation.urihttps://pubs.rsc.org/en/content/articlehtml/2020/dt/d0dt01512acs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/1477-9234/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectSTATE PERTURBATION-THEORYen
dc.subjectINDUCED SLOW RELAXATIONen
dc.subjectMONONUCLEAR COBALT(II) COMPLEXen
dc.subjectTRANSITION-METAL-COMPLEXESen
dc.subjectZERO-FIELDen
dc.subjectLIGAND-FIELDen
dc.subjectHETEROPOLYMETALLIC COMPLEXESen
dc.subjectMAGNETIZATION RELAXATIONen
dc.subjectMOLECULE MAGNETen
dc.subjectHARTREE-FOCKen
dc.titleCo(II)-Based single-ion magnets with 1,1 '-ferrocenediyl-bis(diphenylphosphine) metalloligandsen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-165497en
sync.item.dbtypeVAVen
sync.item.insts2025.02.03 15:50:49en
sync.item.modts2025.01.17 16:52:33en
thesis.grantorVysoké učení technické v Brně. Středoevropský technologický institut VUT. Magneto-Optická a THz Spektroskopiecs
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